Answer:
ethanol
Step-by-step explanation:
Methanol has a boiling point of 65°C, propan-1-ol has a boiling point of 97°C and ethanol has a boiling point of 87°C
Fractional distillation is used for separating miscible liquids through the use of the different vapor pressure properties of the liquids. As the mixture is heated up, components start to vaporize according to their boiling points. The component with the least boiling point vaporizes first while the component with the highest boiling point vaporizes last.
This means that methanol would vaporize at the first fraction because it has the lowest boiling point followed by ethanol at the second fraction and then propan-1-ol at the last fraction.