Question

Compound X has the formula C7H14. X reacts with one molar equivalent of hydrogen in the presence of a palladium catalyst to form 3-methylhexane. Treatment of X with ozone follwed by zinc in aqueous acid gives a ketone plus formaldehyde (CH2=O). What is the structure of X?

Answer 1

Compound X, with the formula C7H14, is likely 1-heptene, an alkene that forms 3-methylhexane upon hydrogenation, and yields a ketone and formaldehyde upon ozonolysis, indicating a terminal double bond.

Step-by-step explanation:

The student asked to determine the structure of compound X with the formula C7H14. Based on the given reactions, we can infer certain structural details about compound X. The reaction with hydrogen in the presence of a palladium catalyst to form 3-methylhexane implies that X must have been an alkene, as alkenes undergo hydrogenation to form alkanes. Since 3-methylhexane is formed, the double bond is located at the third carbon of the heptene chain when numbered to give the lowest possible locants for substituents.

Moreover, when X is treated with ozone followed by zinc in aqueous acid, a ketone and formaldehyde are produced. This suggests that the double bond of X is terminal, meaning it's at the end of the carbon chain, as ozonolysis of terminal alkenes yields formaldehyde and a ketone. Therefore, the structure of X is likely 1-heptene.

Answer 2

3-methylenehexane

Step-by-step explanation:

In this case, we have two clues.

1) The hydrogenation reaction

2) The ozonolysis reaction

See figure 1.

With this in mind, lets analyze each clue. In the first reaction, we know that only 1 molecule of
`H_2` is added to the unknown molecule. This indicates that we only have 1 double bond in the molecule. Now, the next question is where is placed the double bond?

To answer this question, we have to use the second clue. In the ozonolysis reaction, a double bond is broken and is replaced with a carbonyl group. If, formaldehyde is formed the double bond is formed with a primary carbon. The primary carbons in the structure (given in the first reaction: 3-methylhexane) are carbons 1, 6, and 7. So, the double bond can be placed between carbons:

a) 6 and 5

b) 7 and 3

c) 1 and 2

To decide which one is the position of the double bond we have to keep in mind the second product of the ozonolysis reaction a ketone. With this in mind, the carbon bonded to the primary one (deduced by the formaldehyde) it has to be a tertiary carbon. The only option that has a primary carbon bonded to tertiary carbon is b). (See figure 2)

Finally, with this in mind the structure is 3-methylenehexane. To be sure, we can check the formula for the compound,
`C_7H_1_4` and the reactions. (See figure 3)

I hope it helps!