Answer:
You can first pair the numbers so that each pair sum 11: 1 and 10 sums 11, 2 and 9 sums 11, 3 and 8 sums 11, and so on. There are a total of 5 pairs of numbers with the sum being equal to 11.
You can only pick up to 5 numbers without picking any pair: in that case you should select one member of each pair and not the other.
If you select 6 numbers instead of 5 you will have to pick a pair, and then place the other 4 numbers as you wish. This way you can still select up to one pair by placing the 4 remaining numbers each one in a different pair.
However, if you want to place 7 instead of 6, you cant avoid to select the numbers without picking 2 pairs, because the remaining number you have after you have selected six of them in the way we described above (the only way to avoid selecting 2 pairs when you pick 6) will have to go to one of the four incomplete pairs, thus, you will have 2 pairs in your selection.