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To treat a burn on his hand, a person decides to place an ice cube on the burned skin. The mass of the ice cube is 19.2 g, and its initial temperature is − 10.6 ∘ C. The water resulting from the melted ice reaches the temperature of his skin, 29.0 ∘ C. How much heat is absorbed by the ice cube and resulting water? Assume that all of the water remains in the hand.

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Answer : The heat absorbed by the ice cube and resulting water is, 9.15 kJ

Solution :

The process involved in this problem are :


(1):H_2O(s)(-10.6^oC)\rightarrow H_2O(s)(0^oC)\\\\(2):H_2O(s)(0^oC)\rightarrow H_2O(l)(0^oC)\\\\(3):H_2O(l)(0^oC)\rightarrow H_2O(l)(29.0^oC)

The expression used will be:


\Delta H=[m* c_(p,s)* (T_(final)-T_(initial))]+m* \Delta H_(fusion)+[m* c_(p,l)* (T_(final)-T_(initial))]

where,


\Delta H = heat available for the reaction =
4.50* 10^3kJ=4.50* 10^6J

m = mass of ice = 19.2 g


c_(p,s) = specific heat of solid water or ice =
2.01J/g^oC


c_(p,l) = specific heat of liquid water =
4.18J/g^oC


\Delta H_(fusion) = enthalpy change for fusion =
6.01kJ/mole=6010J/mole=(6010J/mole)/(18g/mole)J/g=333.89J/g

Molar mass of water = 18 g/mole

Now put all the given values in the above expression, we get:


\Delta H=[19.2g* 2.01J/g^oC* (0-(-10.6))^oC]+19.2g* 333.89J/g+[19.2g* 4.18J/g^oC* (29.0-0)^oC]


\Delta H=9147.1872J=9.15kJ

Therefore, the heat absorbed by the ice cube and resulting water is, 9.15 kJ

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