Avapor mixture containing 50.0 mole % benzene and 50.0 mole % toluene at 1 atm is cooled isobarically in a closed container from an initial temperature of 115°C. Use the Tsy diagram below to answer the following questions. 115 110 1400 1300 105 100 Vapor 1200 95 Temperature (°C) 90 Liquid 1100 1000 900 Pressure (mm Hg) Liquid 85 800 Vapor 80 700 75 70 600 500 0 1.0 65 0 10 0.2 0.4 0.6 0.8 Mole fraction henvene Polarm 0.2 0.4 0.6 0.8 Mole fraction benzene 7100 First Condensation Your answer is partially correct. At what temperature does the first drop of condensate form? 104 °C What is its composition? 0.20 mol benzene/mol
Last Condensate Your answer is partially correct. At what temperature does the last bubble of vapor condense? °C 98 What is its composition? 0.53 mol benzene/mol