Angle 3 is a vertical angle of angle 1 and will always be identical to what angle 1 is.
Angle 2 and angle 4 are supplementary angles to angle 1 and will always be the difference between 180 and what angle 1 is.
For example if angle 1 was 45 degrees, angle 3 would also be 45 degrees and angle 2 and angle 4 would be 180-45 = 135 degrees.