Two angles are congruent if they are equal and supplementary if there sum is 180.
Given data:
c and d are parallel.
Now

are corresponding angles, so they are equal.
So,

form a congruent pair.
Now since

since they are vertically oppsoye angles.
And,

So,

So,

form a congruent pair.
Now,

So,

form a congruent pair.

So,

form a congruent pair.
Now,

So,

form a supplementary pair.