Use the Law of Sines to find a:

Since both a and the angle A are unkowns, we need to find the measure of the angle opposite to the side A first. Notice that two of the interior angles of the triangle are given. Remember that the sum of the internal angles of every triangle must add up to 180º.
Then:

Then, the angle opposite to the side with length a has a measure of 50º.
Isolate a from the equation of the law of sines and replace A=50º to find the length a:

Therefore, to the nearest tenth, the length of a is equal to 44.1cm.