1) Not chopping off a theif's hand for stealing (many places this is inline with the law).
2) Jaywalking to help an old lady cross the street.
3) Freedom fighters aiding runaway slaves in the days were slavery was inline with the law.
4) Running a red light to get your pregnant wife to the hospital.
5) Torture if you KNEW it would be the only way to get information to stop a terrorist attack.
6) Revolutions in various dictator/autocrat run countries.