Final answer:
The first thing to do when a new system has been assembled is to pressurize the system with an inert gas and leak check.
Step-by-step explanation:
The correct answer is b) pressurize the system with an inert gas and leak check. When a new system has been assembled, it is important to pressurize the system with an inert gas and perform a leak check to ensure that there are no leaks in the system. This step is crucial for the safe and effective operation of the system.