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Consider the structural formulas for methanol, CH_3OH, and ethane, C_2H_6. Which has a higher melting point and which statement substantiates the answer?

A. CH_3OH because it has a hydrogen directly bonded to an oxygen.
B. C_2H_6 because it has hydrogen directly bonded to oxygen.
C. CH_3OH because it has a hydrogen directly bonded to a methyl group.
D. C_2H_6 because all of its hydrogens are directly bonded to carbon.

User Ahmed Negm
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1 Answer

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Final answer:

Methanol has a higher melting point than ethane because it can form strong hydrogen bonds due to the presence of a hydroxyl group, while ethane can exhibit only weaker dispersion forces.

Step-by-step explanation:

Melting Point Comparison of Methanol and Ethane

The melting point of a compound is significantly influenced by the types of intermolecular forces present within the substance. In comparing methanol (CH_3OH) and ethane (C_2H_6), we must consider the molecular structure and the intermolecular forces that each of these compounds can exhibit. Methanol has a hydroxyl group (-OH), which makes it capable of forming hydrogen bonds, a type of strong dipole-dipole interaction. On the other hand, ethane is a nonpolar molecule with only carbon-hydrogen bonds, hence only exhibiting weaker London dispersion forces.

Since hydrogen bonding is significantly stronger than London dispersion forces, methanol will have a higher melting point compared to ethane. Therefore, the correct answer is A. CH_3OH because it has a hydrogen directly bonded to an oxygen, allowing for hydrogen bonding which increases the melting point.

User Localhost
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