Final answer:
(b) H₂O. (water) is an example of a covalent molecule where the molecular shape (bent) differs from the electron pair arrangement (tetrahedral) around the oxygen atom due to lone pair repulsion.
Step-by-step explanation:
To find a molecule or polyatomic ion where the molecular shape is different from the electron arrangement, we consider option (b) H₂O. The molecular formula for water is H₂O, which is a covalent substance.
Water's Lewis structure shows two lone pairs of electrons on the oxygen atom and two bonding pairs, which result in a bent molecular shape due to the electron pair repulsion.
However, if we only consider the electron pair arrangement around the oxygen, we get a tetrahedral arrangement. The molecular geometry of water is different from the electron arrangement primarily because of the repulsions between the two lone pairs and the bonding pairs.