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I've been looking into corrosion and common ways to prevent it. Pure nickel seems to be the main anticorrosive material to use, but I can't find a decent answer as to what it has/does that other metals don't.

One answer I saw is that nickel oxide forms a thin layer and acts as a barrier for corrosion. Does nickel do this before the corrosion process happens? Or is nickel oxide different from other metal oxides? To my knowledge, metal oxides are the product of galvanic corrosion (for the metal being corroded).

User Benosteen
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Final answer:

Nickel is known for its anti-corrosive properties due to its ability to form a stable and protective nickel oxide layer spontaneously upon exposure to oxygen. This barrier prevents further oxidation of the metal underneath, distinguishing it from other metals whose oxides might not be as protective. Nickel's corrosion resistance is a preemptive protection rather than a byproduct of advanced corrosion.

Step-by-step explanation:

Nickel's Role in Corrosion Prevention

Corrosion is a galvanic process involving the deterioration of metals through oxidation. Not all metals corrode at the same rate, and pure nickel is known for its anti-corrosive properties.

This is because nickel, like some other metals, can form a stable oxide layer on the surface, which acts as a barrier to further oxidation. Nickel oxide formation is a protective mechanism that occurs upon exposure to oxygen, not as a consequence of advanced corrosion but as a preemptive means of protection.

Other methods of protecting metals include barrier coatings like paint, plastic, or grease, utilizing cathodic protection, and creating metal alloys. For example, stainless steel is an alloy with added chromium and nickel, giving it enhanced resistance to corrosion. When you mentioned galvanic corrosion, this refers to the process where a metal becomes the anode in a galvanic cell, corroding in favor of protecting another metal that acts as the cathode.

To directly address your question, nickel oxide is different from other metal oxides in the sense that it forms a very stable and adherent layer that prevents further corrosion, unlike the porous and flaky oxide layers that form on some other metals, which can allow continued corrosion. The ability to form such a protective layer is why nickel is regarded as a principal material for anti-corrosive applications.

User Ksice
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