Final answer:
Option (A), In 'The Pilgrim’s Progress' by John Bunyan, Hopeful is the character who eventually joins Christian on his journey. For the related question, ‘greater emphasis on nature’ is not a characteristic of the Second Great Awakening.
Step-by-step explanation:
The character who decides to go with Christian at the beginning of John Bunyan's The Pilgrim's Progress is not explicitly stated in the choices provided. However, throughout the narrative, it is Hopeful who joins Christian on his journey from the City of Destruction to the Celestial City after Christian has already been traveling for a while. None of the other listed characters, Charity, Goodwill, or Evangelist, accompany Christian in the same manner.
Turning to the reference given in regards to the Second Great Awakening, the characteristic that is not associated with it is A. greater emphasis on nature. The Second Great Awakening was a Protestant religious revival during the early 19th century in the United States which emphasized a personal relationship with God, religious education of children, increased church attendance, and a belief in the possibility of creating a better world through personal salvation and social reform.