105k views
0 votes
Instructions

Consider the following information when answering Questions 8-10.
Predictions Based Reduction Potentials
Consider the standard reduction potentials.
A13+ (aq) + 3 e-Al (s)
cost log) từ Co2 lag)
-
Cut (aq)+e-Cu (s)
Mn2+ (aq) +2e →Mn (s)
BACKGROUND
Ered=-1.66V
Ered=+1.84 V
Ered=+0.52 V
Ered=-1.18 V
Reduction potential is the tendency for a species to be reduced (gain electrons) in
a reduction half-reaction. Standard reduction potential (Ered) is the voltage
associated with a reduction reaction at an electrode when all solutes are 1 M and
all gases are at 1 atm at 25°C.
The more positive the value of Ered the greater the tendency for reduction under
standard conditions.
.
Large +Ered values (easily reduced, good oxidizing agents)
• Large-Ered values (easily oxidized, good reducing agents)
Standard cell potential (E cell) can be calculated using the standard reduction
9
0.7 points
Using the list of half-reactions and their standard reduction potentials,
answer the following questions.
Part A: Which is the strongest reducing agent?
choose your answer...
Part B: Which is the stro
Part C: Which of the fol
Part D: Which of the fol
choose your answer.....
Cu (s)
Cu* (aq)
Mn³ (aq)
Al (aq)
Al(s)
Co (aq)
Mn (s)
J?

User Kmangyo
by
7.6k points

1 Answer

5 votes

Final answer:

The strongest reducing agent is Al with an Ered of -1.66V, and the strongest oxidizing agent is Co2+ with an Ered of +1.84V. The standard reduction potential values are indicative of the tendency for a species to be reduced or oxidized, influencing their behavior as either reducing or oxidizing agents.

Step-by-step explanation:

When determining the strongest reducing agent and strongest oxidizing agent from a set of half-reactions, we look at the standard reduction potentials (Ered). The species with the lowest (most negative) Ered value acts as the strongest reducing agent because it has a greater tendency to lose electrons. In contrast, the species with the highest (most positive) Ered value acts as the strongest oxidizing agent because it has a greater tendency to gain electrons.

Based on the given data:

  • A13+ (aq) + 3 e- → Al (s), Ered = -1.66V
  • Co2+ (aq) + 2 e- → Co (s), Ered = +1.84 V
  • Cu2+ (aq) + e- → Cu (s), Ered = +0.52 V
  • Mn2+ (aq) + 2 e- → Mn (s), Ered = -1.18 V

Part A: Al is the strongest reducing agent (most negative Ered).

Part B: Co2+ is the strongest oxidizing agent (most positive Ered).

Applying this concept to predict the spontaneity of redox reactions, a reaction is spontaneous if the cell potential (Ecell) is positive, which occurs when Ered cathode > Ered anode. Hence, a species higher in the table (with higher Ered) is a stronger oxidant than one lower in the table.

User Katsuya Obara
by
7.5k points
Welcome to QAmmunity.org, where you can ask questions and receive answers from other members of our community.