Final answer:
The strongest reducing agent is Al with an Ered of -1.66V, and the strongest oxidizing agent is Co2+ with an Ered of +1.84V. The standard reduction potential values are indicative of the tendency for a species to be reduced or oxidized, influencing their behavior as either reducing or oxidizing agents.
Step-by-step explanation:
When determining the strongest reducing agent and strongest oxidizing agent from a set of half-reactions, we look at the standard reduction potentials (Ered). The species with the lowest (most negative) Ered value acts as the strongest reducing agent because it has a greater tendency to lose electrons. In contrast, the species with the highest (most positive) Ered value acts as the strongest oxidizing agent because it has a greater tendency to gain electrons.
Based on the given data:
- A13+ (aq) + 3 e- → Al (s), Ered = -1.66V
- Co2+ (aq) + 2 e- → Co (s), Ered = +1.84 V
- Cu2+ (aq) + e- → Cu (s), Ered = +0.52 V
- Mn2+ (aq) + 2 e- → Mn (s), Ered = -1.18 V
Part A: Al is the strongest reducing agent (most negative Ered).
Part B: Co2+ is the strongest oxidizing agent (most positive Ered).
Applying this concept to predict the spontaneity of redox reactions, a reaction is spontaneous if the cell potential (Ecell) is positive, which occurs when Ered cathode > Ered anode. Hence, a species higher in the table (with higher Ered) is a stronger oxidant than one lower in the table.