An example of a function φ : C → C that satisfies φ(w + z) = φ(w) + φ(z) for all w, z ∈ C but is not linear is the complex conjugation function.
φ(w) = w*
Where w* is the complex conjugate of w. This function preserves addition but is not linear because it does not satisfy φ(cw) = cφ(w) for all complex numbers c.
Hope this helps! ;)