Answer:
(a) A weak acid is an acid that partially dissociates in water, releasing a small amount of hydrogen ions (H+) and resulting in a pH lower than 7.
(b) The balanced chemical equation for the dissociation of valeric acid is:
CH3(CH2)3COOH (aq) ⇌ CH3(CH2)3COO- (aq) + H+ (aq)
(aq) denotes that the compound is dissolved in water.
(c) The balanced chemical equation for the dissociation of sodium valerate is:
CH3(CH2)3COONa (aq) ⇌ CH3(CH2)3COO- (aq) + Na+ (aq)
(d) A buffer solution is a solution that can resist changes in pH when small amounts of acid or base are added to it. Buffer solutions contain a weak acid and its conjugate base or a weak base and its conjugate acid. The weak acid or base can neutralize any added acid or base, maintaining a stable pH.
(e) A solution of valeric acid and sodium valerate can function as a buffer solution because valeric acid is a weak acid and sodium valerate is its conjugate base. When small amounts of acid are added to the buffer solution, the valeric acid can neutralize it by accepting hydrogen ions, while the sodium valerate can neutralize small amounts of base by releasing hydrogen ions. Additionally, the buffer solution resists changes in pH when small amounts of distilled water are added because the valeric acid and sodium valerate concentrations remain relatively constant. The balanced chemical equations for these reactions are:
(i) Valeric acid + H+ ⇌ CH3(CH2)3COOH2+
(ii) Sodium valerate + OH- ⇌ CH3(CH2)3COOH + NaOH
(iii) CH3(CH2)3COOH ⇌ CH3(CH2)3COO- + H+
(iv) CH3(CH2)3COO- + H+ ⇌ CH3(CH2)3COOH