Final answer:
A bismuth atom, with an atomic number of 83, has a total of 27 electrons occupying its p orbitals, considering the fillings of the 2p, 3p, 4p, 5p, and 6p subshells.
Step-by-step explanation:
The number of electrons that occupy p orbitals in a bismuth atom can be determined by looking at its electron configuration. Bismuth has an atomic number of 83, which means it has 83 electrons. Its electron configuration ends in 6p³. Therefore, to find the total number of electrons in p orbitals, we count all the electrons in the 2p, 3p, 4p, 5p, and 6p orbitals.
Each p subshell can hold a maximum of 6 electrons (2 per each of the three orbitals). The electron configuration reflecting the filling of p orbitals for bismuth is:
2p¶ (6 electrons in 2p)
3p¶ (6 electrons in 3p)
4p¶ (6 electrons in 4p)
5p¶ (6 electrons in 5p)
6p³ (3 electrons in 6p)
Adding these together, 6 + 6 + 6 + 6 + 3 equals 27. Therefore, there are 27 electrons that occupy the p orbitals in a bismuth atom.