Answer: The correct option is C.
Explanation: ppm is used to measure the concentration of solute in a given volume of solution. ppm is basically parts per million.
Mathematically,

We are given:
Mass of methanol =
(Conversion Factor : 1g = 1000mg)
Volume of solution = 250 mL = 0.250L (Conversion Factor : 1L = 1000mL)
Putting values in above equation, we get:

Concentration of methanol = 0.062ppm
Hence, the correct option is C.