In this case, the car slow down from 23m/s into rest which means 0m/s. That mean the average speed of the car would be: (23m/s + 0 ms)/2= 11.5m/s.
If the car moved for 85m with that average speed, then the time car moves would be:
85m/ (11.5m/s)= 7.39s
The car moves for 7.39 second, losing velocity from 23m/s into 0m/s. Then the acceleration would be:
(23m/s - 0m/s)/ 7.39s= 3.11 second