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The critical angle for total internal reflection for a substance is 42.0°. what is the polarizing angle for this substance?

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For the total internal reflection of a substance, we can express the relationship between the critical angle,
\theta_(c), and the indices of refraction as


n_(1) sin(\theta_(c)) = n_(2) (1)

where
n_(1) and
n_(2) are the indices of refraction. And under polarization, we can express Snell's Law as


n_(1) sin(\theta_(p)) = n_(2)sin(90-\theta_(p))

Rearranging this we have


n_(1) sin(\theta_(p)) = n_(2)cos(\theta_(p))

(sin(\theta_(p))/(cos(\theta_(p))) = (n_(2))/(n_(1))

tan(\theta_(p)) = (n_(2))/(n_(1)) (2)

Substituting equations (1) into (2), we have


tan(\theta_(p)) = (n_(1) sin(\theta_(c)))/(n_(1))

tan(\theta_(p)) = sin(\theta_(c))

Substituting the value of the critical angle, we have


tan(\theta_(p)) = sin(42)

\theta_(p) = tan^(-1)(sin42) = 33.79

Answer: 33.79°
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