The chance of the first student chosen not secretly being a robot is 2/6, but if the student is secretly a robot, then it doesn’t matter who the second student chosen is, because “neither” cannot be obtained.
So, 2/6th the time we care about the second student. There is in this case 1 non robot among the 5 remaining students, so the chance is 1/5 of picking that second non robot.
Hence;
2/6 x 1/5 = 2/30 = 1/15