Answer:
Option (4).
Step-by-step explanation:
Enzymes are bio catalyst that can increase the rate of chemical reaction without itself going any change in the reaction. Activation energy is the minimum amount of energy required to convert the reactant into the product.
Enzymes lower the activation energy of a reaction by binding with the one of the substrate (reactant) of the reaction. The enzymes increases the effective collision of the reaction and increases the rate of a reaction.
Thus, the correct answer is option (4).