Final answer:
Approximately 7589.9 mL of pure liquid methanol are needed to prepare 500.0 mL of a 12.0 g/L methanol solution.
Step-by-step explanation:
To calculate the volume of liquid methanol needed to prepare the aqueous solution, we can use the equation:
mass of methanol (g) = volume of methanol (mL) * density of methanol (g/mL)
First, we need to convert the mass of methanol in the solution to grams:
mass of methanol (g) = 500.0 mL * 12.0 g/L = 6000.0 g
Next, we can use the density of methanol to find the volume of pure liquid methanol needed:
volume of methanol (mL) = mass of methanol (g) / density of methanol (g/mL) = 6000.0 g / 0.791 g/mL = 7589.9 mL
Therefore, approximately 7589.9 mL of pure liquid methanol are needed to prepare 500.0 mL of the 12.0 g/L methanol solution.