You must add 75 mL water to 195 mL 90 % alcohol to make 270 mL of 65 % alcohol.
Step 1. Calculate the volume of 90 % alcohol needed
You can use the dilution formula
V1×C1 = V2×C2
where
V1 and V2 are the volumes of the two solutions
C1 and C2 are the concentrations
You can solve the above formula to get
V2 = V1 × C1/C2
V1 = 270 mL; C1 = 65 %
V2 = ?; _____C2 = 90 %
∴V2 = 270 mL × (65 %/90 %) = 195 mL
You need 195 mL of 90 % alcohol to make 270 mL of 65 % RA
Step 2. Calculate the amount of water to add.
Volume of water = 270 mL – 195 mL = 75 mL