Please find the attached diagram for a better understanding of the question.
For solving this question we will make use of a theorem which says: Tangent-chord angles are equal to half the measure of the intercepted arc.
Thus, if we use this theorem in our diagram, we will arrive at this equation:-

Now, we are given that
(please note that
is the angle between the tangent and the chord.)
Therefore,

Thus,

Or

Therefore, we conclude that Option D is the correct answer.