Answer:
See explanation below
Step-by-step explanation:
The equation to use for this is the following:
dU = q + w
As the heat is being release, this value is negative, and same here happens with the work done, because it's in the surroundings.
Therefore the change in the energy would be:
dU = -2.59x10^4 - 6.46^4
dU = -9.05x10^4 kJ