To solve this problem it is necessary to apply the Snell Law. With which the angles of refraction and incidence on two materials with a determined index of refraction are described.
The equation stipulates that

Where,
= Index of refraction of each material
Angle of incidence or Angle of Reflection
Angle of refraction
Our values are given as,
Index of refraction of water


Replacing we have that,




Therefore the angle of reflection is 20.93°