Explanation:
On a field every element different from 0 should have a multiplicative inverse. Let's check that in Z2[i] not ALL nonzero elements have multiplicative inverses.
Z2 is made of two elements: 0 and 1, and so Z2[i] is made of four elements: 0+0i,0+1i, 1+0i, 1+1i (which we can simplify from now on as 0, i, 1, 1+i respectively). Now, let's check that the element 1+i doesn't have a multiplicative inverse (we can do this by showing that no matter what we multiply it by, we're not getting 1, which is the multiplicative identity)
(which is NOT 1)
(which is NOT 1) (remember -1 and 1 are the same in Z2)
(which is NOT 1)
(which is NOT 1) (remember 2 is the same as 0 in Z2)
Therefore the element 1+i doesn't have a multiplicative inverse, and so Z2[i] cannot be a field.