Answer:
Yes, it's possible.
Explanation:
We know that a linear system has a unique solution if it has the same number of equations than variables (but remember that you musn't have a linear combination of equations).
So it is possible to create a system with more equations than variables, with a unique solution.
Example:
1) X + Y + Z = 3
2) 2X + 2Y + 2Z = 6
3) X + Y = 2
4) X + Z = 2
This is a 4 equation and 3 variable system. Pay attention to equation number 1) and 2). They are a linear combination (number 2 is the number 1 multiplied by 2). So, for this system you can basically ignore one of them.
If you do that, you will have 3 equations and 3 variables, with a unique solution. In this case solution is X = 1, Y = 1, Z = 1.
Now, let's see if equation number 2 satisfies:
2x1 + 2x1 + 2x1 = 6
6 = 6
With this simple example we proved that you can have a linear system with a unique solution if it has more equations than variables.