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What effect does a lone electron pair have on molecular shape?

A. The lone pair has no effect on shape.
B. The lone pair pushes bonding electron pairs away.
C. The lone pair stretches atomic bonds.
D. The lone pair forces atoms closer to the nucleus.

User Khary
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1 Answer

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Final answer:

A lone electron pair affects the molecular shape by pushing bonding electron pairs away, altering the molecular geometry and reducing bond angles.

Step-by-step explanation:

The lone electron pair on the central atom in a molecule affects the molecular shape by causing a repulsion that pushes bonding electron pairs away. This results in a distortion of the idealized molecular geometry to accommodate the space lone pairs occupy. The presence of a lone pair reduces the bond angle between adjacent bonding pairs, altering the electron-pair geometry and molecular structure. For instance, in the molecular geometry designated as AX₂E, where E represents a lone pair, the structure shows that a lone pair occupies more space around the central atom than a bonding pair. This is due to the fact that a lone pair is not shared between two nuclei, creating greater repulsion when compared to bonding pairs. Therefore, the correct answer to the student's question is:

B. The lone pair pushes bonding electron pairs away.

User Aspen
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