a) In 25 grams of water, the solubility is 92/4 = 23 grams, so adding 24 grams will produce a supersaturated solution.
b) In 50 grams of water, the solubility is 92/2 = 46 grams, so adding 47 grams will produce a supersaturated solution.
c) In 150 grams of water, the solubility is 92(1.5) = 138 grams, so adding 127 grams will produce an unsaturated solution.