Heavier compounds tend to have higher boiling points. However, sulphur dichloride (Mr= 103.1 gmol-1) and sulphur hexafluoride (Mr = 146.1 g mol-1) have the boiling point of 59 °C and -50.8 °C respectively.

Heavier compounds tend to have higher boiling points. However, sulphur dichloride (Mr= 103.1 gmol-1) and sulphur hexafluoride (Mr = 146.1 g mol-1) have the boiling point of 59 °C and -50.8 °C respectively. Explain this phenomenon.

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