Final answer:
To find the density of a 50.0% KOH solution with a 13.39 M concentration, multiply the molarity by the molar mass of KOH to get mass per liter, and then double it for a 50% solution by mass to obtain the density.
Step-by-step explanation:
The density of a solution that is 50.0% KOH by mass with a concentration of 13.39 M can be determined using the mass percentage, the molarity, and the molar mass of KOH. First, we calculate the mass per liter of the solution from the molarity:
Mass per liter = Molarity (M) × Molar mass (g/mol)
For KOH:
Molar mass of KOH = 39.1 (K) + 16.0 (O) + 1.0 (H) = 56.1 g/mol
Using the molarity, we find the mass per liter of the solution:
Mass per liter = 13.39 M × 56.1 g/mol = 751.449 g/L
Since 50% of the mass is KOH, we double the mass per liter to find the density:
Density = 751.449 g/L × 2 = 1502.898 g/L or 1.502898 g/cm³