We are given:
Mass of Na added = 4.35 grams
Mass of water = 105 grams
Mass Percent of Na:
Total mass of the solution = mass of solute + mass of solvent
Total mass of the solution = 4.35 + 105 = 109.35 grams
Mass percent of solute = (mass of solute / mass of solution) * 100
Mass percent of Solute = (4.35 / 109.35) * 100
Mass percent = 3.978 %