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When a 1.00-g sample of methane gas was burned with excess oxygen in the calorimeter, the temperature increased by 7.3°C. When

a 1.00-g sample of hydrogen gas was burned with excess oxygen, the temperature increase was 14.3°C. Compare the energies of
combustion (per gram) for hydrogen and methane.
a. 10kJ CH4, 100kJ H2.
b. 160kJ CH4, 80kJ H2
c. 80kJ CH4, 160kJ H2-
d. 100kJ CH4, 10k) H2

User Odrakir
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1 Answer

4 votes

Answer:

The energies of combustion (per gram) for hydrogen and methane are as follows: Methane = 82.5 kJ/g; Hydrogen = 162 kJ/g

Note: The question is incomplete. The complete question is given below:

To compare the energies of combustion of these fuels, the following experiment was carried out using a bomb calorimeter with a heat capacity of 11.3 kJ/℃. When a 1.00-g sample of methane gas burned with

excess oxygen in the calorimeter, the temperature increased by 7.3℃. When a 1.00 g sample of hydrogen gas was burned with excess oxygen, the temperature increase was 14.3°C. Compare the energies of combustion (per gram) for hydrogen and methane.

Step-by-step explanation:

From the equation of the first law of thermodynamics, ΔU = Q + W

Since there is no expansion work in the bomb calorimeter, ΔU = Q

But Q = CΔT

where C is heat capacity of the bomb calorimeter = 11.3
kJ/ºC; ΔT = temperature change

For combustion of methane gas:

Q per gram = (
11.3
kJ/ºC * 7.3°C)/1.0g

Q = 83 kJ/g

For combustion of hydrogen gas:

Q per gram = (
11.3
kJ/ºC * 14.3°C)/1.0g

Q = 162 kJ/g

User Apen
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