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) Chromate/Dichromate Equilibrium. Yellow chromate ion reacts with hydrogen ion to form (by condensation and loss of H2O) the orange dichromate ion:

User Douwe Maan
by
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1 Answer

6 votes

Answer:

Step-by-step explanation:

The Chromite ore is used for the production of Chromate/dichromate formation.


4FeCr2O4 + 8Na2CrO4+7O2 \\
8NaCrO4 +2Fe2O3 +8CO2\\yellow

so
Na2CrO4 is called Chromite ore which is of yellow color.


Na2CrO4 +2H^+
Na2CrO4 +2Na^+ +H2O


Orange

so when sodium chromate is reacted with hydrogen ion it forms sodium dichromate which is of orange color

Now


Na2Cr2O7+2KCl
K2Cr2O7 + NaCl

The chromate and dichromate are interconvertible in aqueous solution depending upon the PH of solution

Acid medium:
Cr2O4^2-
2H^+
Cr2O7^2-
+H2O

Base:
Cr2O7^2- +2OH^-
CrO4^2- +H2O

Hence Chromate and dichromate are interconvertible and hold and equilibrium.

User Aleksei Zyrianov
by
8.3k points
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