Answer:
= 6.21x10^21
Step-by-step explanation:
It's the train track method, where you try to cancel all the units and end with units that you need. Here we want to end with number of atoms of N.
500 mg N x 1 g N/1000 mg N x 1 mol N/194.19 g N x 4 mol N/1 mol of caffeine x (6.022 x 10^23 particles of N / 1 mol N)
= 6.21x10^21