Answer:
corrected pressure : unknown 1 = 2.452 Atm, unknown 2 = 1.088 atm
number of moles : unknown 1 = 0.079 moles unknown 2 = 0.035263 moles
Step-by-step explanation:
Given data:
volume pressure = 0.785 liters
Unknown 1 = 1884 torr (1884 mmhg )
Unknown 2 = 847 torr ( 847 mmhg )
vapor pressure at 22⁰c = 19.8 mmhg
Determine the number of moles of H2 gas for the unknowns
unknown corrected pressure for unknown 1 = total pressure - vapor pressure = 1884 - 19.8 = 1864.2 mmhg / 760 = 2.452 Atm
no of moles = PV / RT
T = 22 + 273.15 = 295.15 k
P = 2.452 atm
R = 0.08206L.atm/mole.K
v = 0.785
number of moles = (2.452 * 0.785 ) / (0.08206 * 295.15 ) = 0.079 moles of
Unknown corrected pressure for unknown 2 = total pressure - vapor pressure = (847 - 19.8 ) / 760 = 1.088 atm
number of moles = PV / RT
T = 22 + 273.15 = 295.15 k
R = 0.08206L.atm/mole.K
v = 0.785
P = 1.088 atm
number of moles = (1.088 * 0.785 ) / (0.08206 * 295.15 ) = 0.035263 moles
B ) determine the ratio of sample mass to number of moles
molar mass of H2 = 2.01588 g/mole
for unknown 1 = 2.01588 / 0.079 = 25.51
for unknown 2 = 2.01588 / 0.035263 = 57.167