if an ordered pair is a solution, it should satisfy the equation.
see the first option
, if you put $x=4$ and $y=12$
you'll get $12=12$ which is true.
now the last option, $y=8-x$ put $x=4$ and $y=12$
$12=8-4\implies 12\\e4$ thus it is not a solution.
So option 4 is correct