Answer:
(i) False
(ii) Selecting a 5 or a spade are not independent.
Explanation:
(i)
Independent events are those events that occur at the same time, i.e. the occurrence of one event does not effects the occurrence of the other.
If A and B are independent events then:
Whereas as if two events are mutually exclusive, then the probability of them both taking place at the same time is 0.
Then for events A and B:

Thus, the statement is False.
(ii)
In a standard deck of 52 cards there are:
Spades = 13
Diamond = 13
Heart = 13
Clubs = 13
And each of these 13 cards are:
K, Q, J, 10, 9, 8, 7, 6, 5, 4, 3, 2, A
If a card labelled as 5 is selected then it could also be a Spade.
And if a spade is selected then the card could be labelled as 5.
So, selecting a 5 or a spade are not independent.