First, we find the molar mass of KCl which is AK+ACl=39+35.5=74.5g/mole
now we find out the number of moles by dividing the given mass to the molar mass n=m/M=19.9/74.5=0.26 moles. The molarity of a solution is equal to the number of moles divided by the volume of the solution. =0.26moles/0.75liters=0.346M