Answer
42
Explanation
Let’s say:
Set of envelopes: {a,b,c,d,e,f,g}
Set of postage stamps: {1,2,3,4,5,6}
For an envelope you can have:
1a 2a 3a 4a 5a 6a (6 different combinations)
This applies to all 7 different types of envelopes.
Therefore 7 • 6 = 42