Answer: 1.29 moles of ethylene glycol must be added to 1 kg of water to make a solution with a freezing point of -2.4°C. Molality of solution is 1.29 m.
Step-by-step explanation:
Depression in freezing point is given by:
![\Delta T_f=i* K_f* m](https://img.qammunity.org/2021/formulas/chemistry/college/olviivbff943k0sgn1jey0npv1smz5xyo2.png)
= Depression in freezing point
i= vant hoff factor (for non electrolyte , i = 1)
= freezing point constant for water=
![1.86^0C/kgmol](https://img.qammunity.org/2021/formulas/chemistry/high-school/72pczx834tmnit9o8c2pi8020ujioc5lj9.png)
m= molality =
![\frac{\text{moles of solute}}{\text{weight of solvent in kg}}](https://img.qammunity.org/2021/formulas/chemistry/high-school/hh2b3el6wl1fvyx95d950nictdgw8o6a7b.png)
m= molality =
![(x)/(1kg)](https://img.qammunity.org/2021/formulas/chemistry/high-school/qoo5i7tisk37ntbrb0q29r79ocjmfgovhl.png)
![2.4^0C=1* 1.86^0C/kgmol* (x)/(1kg)](https://img.qammunity.org/2021/formulas/chemistry/high-school/l27sp51qyz5xvx8act7kky642le9za7srr.png)
![x=1.29](https://img.qammunity.org/2021/formulas/mathematics/middle-school/zvrfwbytpw2kfg6jsuvq1vmncluuiil0v7.png)
Molality =
![\frac{\text{moles of solute}}{\text {weight of solvent in kg}}=(1.29mol)/(1kg)=1.29m](https://img.qammunity.org/2021/formulas/chemistry/high-school/cp0ls2k78z5fu2vax4fanfduktlsnd9v1x.png)
Thus 1.29 moles of ethylene glycol must be added to 1 kg of water to make a solution with a freezing point of -2.4°C. Molality of solution is 1.29 m.