The inclusion-exclusion principle says
P(A1 ∩ A2) = P(A1) + P(A2) - P(A1 ∪ A2)
We know the probability of intersection is 0, so
P(A1) + P(A2) = P(A1 ∪ A2)
which means A1 and A2 are indeed mutually exclusive.
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