Question

Use the formation reactions below such that when added together, they match the balanced equation for the combustion of methane.

Cgraphite(s)+ 2H2(g) → CH4(g) ΔH 1=−74.80kJ
Cgraphite(s)+ O2(g) → CO2(g) ΔH2=−393.5k
H2(g)+ 1/2O2(g) → H2O(g) ΔH3=−241.80kJ
Calculate ΔHrxn for the combustion of methane, CH4(g).
CH4(g)+ 2O2(g) → CO2(g)+ 2H2O(g) ΔHrxn =--------------kJ

Answer 1

ΔH of the reaction is -802.3kJ.

Step-by-step explanation:

Using Hess's law, you can know ΔH of reaction by the sum of ΔH's of half-reactions.

Using the reactions:

(1) Cgraphite(s)+ 2H₂(g) → CH₄(g) ΔH₁ = −74.80kJ

(2) Cgraphite(s)+ O₂(g) → CO₂(g) ΔH₂ = −393.5k J

(3) H₂(g) + 1/2 O₂(g) → H₂O(g) ΔH₃ = −241.80kJ

The sum of (2) - (1) produce:

CH₄(g) + O₂(g) → CO₂(g) + 2H₂(g) ΔH' = -393.5kJ - (-74.80kJ) = -318.7kJ

And the sum of this reaction with 2×(3) produce:

CH₄(g) + 2 O₂(g) → CO₂(g) + 2H₂O(g) And ΔH = -318.7kJ + 2×(-241.80kJ) =

-802.3kJ