Answer: 85.62 L represents volume (V).
Step-by-step explanation:
Volume is defined as the amount or quantity of a given substance or an object.
According to ideal gas equation:

P = pressure of gas = 4.95 atm
V = Volume of gas = 85.62 L
n = number of moles
R = gas constant =

T =temperature =

Thus 85.62 L represents volume (V).