Answer:
2-Methyl-5-nitrothiophene
Step-by-step explanation:
The 2- and 5-positions of thiophene are the most susceptible to electrophilic aromatic substitution.
Thus, the major product from the reaction of 2-methylthiophene with HNO₃ in acetic acid is 2-methyl-5-nitrothiophene.