Answer:
Yes, melting sugar causes the breaking of intramolecular bonds
Step-by-step explanation:
Sugar is the common name for sucrose, C₁₂H₂₂O₁₁ consists of one fructose and one glucose molecule combined together.
When heated, sucrose undergoes "apparent melting" or "inversion". That is during melting, the glucose and fructose in sugar decompose and caramelize in two phases.
Phase one consists of the structural whereby the sugar changes from solid crystal into more liquid form by breaking structural bonds
On further heating, phase two, consists of the removal of water molecules from the sugar. Therefore more intramolecular bonds are broken to release the water molecules.